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We know that split ends are more likely to occur in weathered and oxidized hair. But, split ends happen when the cuticle is removed (damaged) and the cortex-cortex CMC serves as a route for the propagation of axial splits in the fiber, leading to the formation of cracks and split ends. Hair strength depends on cuticle integrity and amount of water in the fibers, conditions that are related to chemical damage. Chemical damage by bleaches, dyes, straighteners and even sunlight can weaken hair and increase inter-fiber friction, leading to breakage. An important factor involved in hair breakage is the occurrence of tangles created by combing forces. Where the break occurs along the fiber, correspond to the point of higher combing forces. The type of fracture depends on hair condition and wet versus dry combing or brushing. Combing dry hair is more related to short segment breaks, and wet combing is related to long segment breaks. The short segment breaks are more related to split ends. Straight to wavy hair combed dry, produces higher end pick forces than mid-length forces, but when wet, produces higher mid-length combing forces corresponding to where hair breaks and to the amount of breakage. The work of combing highly coiled hair is lower wet than dry. The reverse holds for wavy to straight hair. Split ends form more readily from the abrasion (friction) in combination with torsional deformations (grooming and styling). Splitting occur when the cuticle is damaged and weakened. Crack is formed in the cortex. Few cuticle layers do not hold the ends of the hair fiber together. Also, highly oxidized cortex cell membrane by free radical chemistry is more susceptible to split. Hair treated with free radical cosmetics and exposed to sunlight is susceptible to splitting.[5,8,38]




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